PIERCE & STEVENS CHEMICAL -- BARGE ALL PURPOSE CEMENT - ADHESIVE MATERIAL SAFETY DATA SHEET NSN: 8040011974186 Manufacturer's CAGE: 77282 Part No. Indicator: A Part Number/Trade Name: BARGE ALL PURPOSE CEMENT =========================================================================== General Information =========================================================================== Item Name: ADHESIVE Company's Name: PIERCE AND STEVENS CHEMICAL CORP. Company's Street: 710 OHIO ST Company's City: BUFFALO Company's State: NY Company's Country: US Company's Zip Code: 14203-3112 Company's Emerg Ph #: 718-856-4910 Company's Info Ph #: 718-856-4910 Distributor/Vendor # 1: FRANKFORD LEATHER CO Distributor/Vendor # 1 Cage: 7K308 Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 001 Status: SM Date MSDS Prepared: 18FEB89 Safety Data Review Date: 09APR90 Supply Item Manager: KX MSDS Serial Number: BHNJP Hazard Characteristic Code: F3 Unit Of Issue: GL Unit Of Issue Container Qty: 1 GALLON Type Of Container: CAN Net Unit Weight: 7.6 LBS =========================================================================== Ingredients/Identity Information =========================================================================== Proprietary: NO Ingredient: TOLUENE (SARA III) Ingredient Sequence Number: 01 NIOSH (RTECS) Number: XS5250000 CAS Number: 108-88-3 OSHA PEL: 200 PPM/150 STEL ACGIH TLV: 50 PPM; 9293 ------------------------------------- Proprietary: NO Ingredient: ETHYL ACETATE (SARA III) Ingredient Sequence Number: 02 NIOSH (RTECS) Number: AH5425000 CAS Number: 141-78-6 OSHA PEL: 400 PPM ACGIH TLV: 400 PPM; 9192 ------------------------------------- Proprietary: NO Ingredient: NAPHTHA (PETROLEUM SPIRITS OR BENZIN) Ingredient Sequence Number: 03 NIOSH (RTECS) Number: SE7555000 CAS Number: 8030-30-6 OSHA PEL: 100 PPM ACGIH TLV: NOT ESTABLISHED ------------------------------------- Proprietary: NO Ingredient: SILICA, CRYSTALLINE - QUARTZ Ingredient Sequence Number: 04 NIOSH (RTECS) Number: VV7330000 CAS Number: 14808-60-7 OSHA PEL: SEE TABLE Z3 ACGIH TLV: 0.1 MG/M3 RDUST;9293 =========================================================================== Physical/Chemical Characteristics =========================================================================== Appearance And Odor: LIQUID. Boiling Point: 168-475F Vapor Density (Air=1): > 1 Specific Gravity: 0.91 =========================================================================== Fire and Explosion Hazard Data =========================================================================== Flash Point: 25F/-3.8C Flash Point Method: SCC Extinguishing Media: USE CLASS B EXTINGUISHERS: CARBON DIOXIDE, ALCOHOL FOAM. POLYMER FOAM IS PREFERRED DOR LARGE FIRES. Special Fire Fighting Proc: FIREFIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS. WATER MAY BE INEFFECTIVE BUT MAY BE USED TO COOL EXPOSED CONTAINERS TO PREVENT PRESSURE BUILDUP. Unusual Fire And Expl Hazrds: DURING EMERGENCY CONDITIONS, OVEREXPOSURE TO DECOMPOSTION PRODUCTS MAY CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE APPARENT. OBTAIN MEDICAL ATTEMTION. =========================================================================== Reactivity Data =========================================================================== Stability: YES Cond To Avoid (Stability): AVOID EXCESSIVE HEAT AND SOURCES OF IGNITION. Materials To Avoid: STRONG ACIDS OR ALKALINE MATERIALS. Hazardous Decomp Products: SMOKE,CARBON MONOXIDE AND CARBON DIOXIDE; IN ADDITION, HYDROGEN CHLORIDE, CHLORINE MAY BE GENERATED. Hazardous Poly Occur: NO Conditions To Avoid (Poly): NOT APPLICABLE =========================================================================== Health Hazard Data =========================================================================== Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: NO Health Haz Acute And Chronic: REPEATED EXPOSURE TO CRYSTALLINE SILICA MAY CAUSE PNEUMOCONIOSIS, A PROGRESSIVELY DISABLING LUNG DISEASE. REPEATED OVEREXPOSURE TO TOLUENE MAY CAUSE LIVER DAMAGE. Carcinogenicity - NTP: NO Carcinogenicity - IARC: YES Carcinogenicity - OSHA: NO Explanation Carcinogenicity: LISTED BY IARC AS "PROBABLY CARCINOGENIC TO HUMANS WITH LIMITED EVIDENCE" Signs/Symptoms Of Overexp: MOSE OR THROAT IRRITATION, CENTRAL NERVOUS SYSTEM DEPRESSION, HEADACHE, DIZZINESS, NAUSEA, VOMITING. ASPIRATION MATERIAL INTO LUNG MAY CAUSE CHEMICAL PNEUMONITIS WHICH MAY BE FATAL. Med Cond Aggravated By Exp: PREXISTING RESPIRATORY CONDITIONS MAY BE AGGRAVATED BY EXPOSURE TO CRYSTALLINE SILICA. Emergency/First Aid Proc: INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING. GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL ATTENTION. =========================================================================== Precautions for Safe Handling and Use =========================================================================== Steps If Matl Released/Spill: SMALL SPILL: WIPE/SOAK UP WITH PAPER TOWEL OR INERT ABSORBANT. PUT IN DISPOSAL CONTAINER. REMOVE RESIDUE WITH WATER. LARGE SPILL: EVACUATE AND VENTILATE AREA. IF POSSIBLE, STOP LEAK. DIKE TO RETAIN RUN OFF. VACUUM UP FREE LIQUID. ABSORB/WASH RESIDUE. Neutralizing Agent: NOT APPLICABLE. Waste Disposal Method: DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS. Precautions-Handling/Storing: DO NOT STORE ABOVE 95 DEGREES F. STORE LARGE QUANTITIES IN COMPLIANCE WITH OSHA 29CFR1910.106. Other Precautions: DO NOT TAKE INTERNALLY. DO NOT BREATHE MIST. AVOID PROLONGED OR REPEATED BREATHING OF VAPOR. EMPTY CONTAINERS MUST NOT BE WASHED AND REUSED FOR ANY PURPOSE. CONTAINERS SHOULD BE GROUNDED AND BONDED. DO NOT WELD,BRAZE OR CUT ON EMPTY CONTAIN =========================================================================== Control Measures =========================================================================== Respiratory Protection: IF VENTILATION DOES NOT MAINTAIN INHALATION EXPOSURES BELOW PEL(TLV), USE NIOSH/MSHA APPROVED ORGANIC VAPOR CARTRIDGE AND DUST/MIST PRE-FILTER RESPIRATORS AS PER CURRENT 29 CFR 1910.134, INSTRUCTIONS/WARNINGS AND NIOSH-RESPIRATOR SELECTION. Ventilation: MECHANICAL (GENERAL) ROOM VENTILATION IS NORMALLY ADEQUATE. LOCAL EXHAUST MAY BE REQUIRED IF WORK AREA NOT VENTED. Protective Gloves: RUBBER GLOVES. Eye Protection: SAFETY GOGGLES WITH OPTIONAL FACE SHIELD Other Protective Equipment: EYE WASH STATION AND SAFETY SHOWER. INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED. Work Hygienic Practices: OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. =========================================================================== Transportation Data =========================================================================== Trans Data Review Date: 90099 DOT PSN Code: AFR DOT Proper Shipping Name: ADHESIVES, DOT Class: 3 DOT ID Number: UN1133 DOT Pack Group: II DOT Label: FLAMMABLE LIQUID IMO PSN Code: AIH IMO Proper Shipping Name: ADHESIVES, * IMO Regulations Page Number: 3174 IMO UN Number: 1133 IMO UN Class: 3.2 IMO Subsidiary Risk Label: - IATA PSN Code: AKY IATA UN ID Number: 1133 IATA Proper Shipping Name: ADHESIVES IATA UN Class: 3 IATA Label: FLAMMABLE LIQUID AFI PSN Code: AKY AFI Prop. Shipping Name: ADHESIVES AFI Class: 3 AFI ID Number: UN1133 AFI Pack Group: II AFI Label: FLAMMABLE LIQUID AFI Basic Pac Ref: 7-8 Additional Trans Data: CONTAINS TOLUENE, ETHYL ACETATE, VM&P NAPHTHA, ETC. =========================================================================== Disposal Data =========================================================================== =========================================================================== Label Data =========================================================================== Label Required: YES Technical Review Date: 09APR90 MFR Label Number: NONE Label Status: F Common Name: BARGE ALL PURPOSE CEMENT. Chronic Hazard: YES Signal Word: WARNING! Acute Health Hazard-Slight: X Contact Hazard-Slight: X Fire Hazard-Moderate: X Reactivity Hazard-Moderate: X Special Hazard Precautions: MAY BE POISONOUS IF INHALED OR ABSORBED THROUGH SKIN. VAPORS MAY CAUSE DIZZINESS OR SUFFOCATION. CONTACT MAY IRRITATE OR BURN SKIN AND EYES. FIRE MAY PRODUCE IRRITATING OR POISONOUS GASES. RUNOFF FROM FIRE CONTROL OR DILUTION WATER MAY CAUSE POLLUTION. Protect Eye: Y Protect Skin: Y Protect Respiratory: Y Label Name: PIERCE & STEVENS CHEMICAL CORP. Label Street: 710 OHIO STREET Label City: BUFFALO Label State: NY Label Zip Code: 14203-3112 Label Country: US Label Emergency Number: 718-856-4910 ======================================================================= URL for this msds http://siri.org. If you wish to change, add to, or delete information in this archive please sent updates to dan@siri.org.